Lithium-ion batteries power applications ranging from electric mobility to industrial backup systems. Despite their reliability, several failure modes frequently appear across different lithium chemistries such as NMC, LFP, NCA, and LMO.
Each failure has its own mechanism, detection method, and mitigation strategy.
This article summarizes five common, engineering-verified failure scenarios, together with real-world test insights and practical diagnostics.
For readers looking for deeper BMS fundamentals, see our guide:What is a Battery Management System (BMS)?
Causes: Charging beyond $4.2V$ (per cell) or discharging below $2.5V$ due to faulty chargers or BMS failure.
Diagnosis: Using a multimeter to check voltage; the battery may feel unusually hot during charging or fail to hold a charge.
Prevention: Use high-quality BMS (Battery Management Systems) and certified chargers with automatic shut-off features.
Solutions: For mild over-discharge, some "smart chargers" can attempt a low-current recovery (Pre-charge mode). If the cell is dead, it must be replaced.

Causes: Gas buildup (CO, $CO_2$) from electrolyte decomposition caused by heat, overcharging, or age.
Diagnosis: Visible bulging of the casing; the battery feels "spongy" to the touch; device screens may be pushed out of place.
Prevention: Avoid storing batteries in high-temperature environments (e.g., inside a hot car) and avoid physical impacts.
Solutions: No repair possible. Stop using immediately. Do not puncture. Dispose of it at a hazardous waste facility.

Causes: Formation of the SEI (Solid Electrolyte Interphase) layer consuming active lithium; structural degradation of electrodes over hundreds of cycles.
Diagnosis: The battery percentage drops much faster than when new; increased "Internal Resistance" (IR) measured by professional testers.
Prevention: Maintain the "Golden Range" of $20\%$ to $80\%$ charge; avoid "Fast Charging" as the primary charging method.
Solutions: Recalibrate the battery (full charge/discharge cycle) to sync the software with hardware, but physical capacity loss is permanent.

Causes: Variations in internal resistance or self-discharge rates between individual cells in a multi-cell pack.
Diagnosis: Checking individual cell voltages with a battery checker; the pack shuts down even when the total voltage seems "okay."
Prevention: Use matched cells (same batch/brand) when building packs; ensure the BMS has a "Balance" function.
Solutions: Perform a "Top Balance" using a specialized balance charger or manually charging low-voltage cells to match the others.

Causes: Internal short circuits (dendrites), external short circuits, or extreme heat leading to an uncontrollable chemical chain reaction.
Diagnosis: Rapid temperature spike, hissing sounds, release of smoke (often smelling like organic solvents), or fire.
Prevention: Use flame-retardant enclosures; ensure proper ventilation; avoid using damaged or dropped batteries.
Solutions: Use a Class D fire extinguisher or large amounts of water (to cool the surrounding cells). Once it starts, it is difficult to stop; evacuation is the priority.

Q1: Can I still use a battery that has slightly swollen?
No. Any degree of swelling indicates internal chemical damage. It is a ticking time bomb and should be decommissioned immediately.
Q2: Does "Fast Charging" damage my battery?
Frequent fast charging generates more heat and can accelerate capacity loss. It is best used sparingly rather than for every charge.
Q3: How do I store a lithium battery for a long time?
Store it at approximately $40\%$ to $50\%$ charge in a cool, dry place. Never store it fully empty or fully charged for months.
Q4: Is a "dead" lithium battery truly empty?
No, it still contains energy. Even if it doesn't power your device, it can still cause a fire if punctured or crushed.